Effects of temperature on phosphate sorption isotherms and phosphate desorption

Abstract

Abstract Phosphorus sorption isotherms were constructed for two Idaho soils with widely different chemical properties. The soils were equilibrated with various amounts of Ca(H2PO4)2 in 0.01 M CaCl2 for 1, 3, 7, and 11 days at temperatures of 5°C and 20°C. The two soils which had been equilibrated previously for 11 days at 20°C with various amounts of Ca(H2PO4)2 in 0.01 M CaCl2 were desorbed at 5°C and 20°C. The rates of sorption and desorption were decreased as the equilibration temperatures were lowered. The effect of temperature on these processes was detected during the first day of equilibration. Less P was found in the equilibrating solution at the lower temperature. The two soils varied widely in sorption and desorption properties.