Concepedia

Structure of the compound purported to be NN-bis(chloromethyldimethylsilyl)-acetamide: X-ray crystal structure analysis of the novel five-membered oxygen-, silicon-, and nitrogen-containing heterocycle (O–Si)-chloro-[(N-chlorodimethylsilylacetamido)methyl]dimethylsilane

Kay D. Onan, Andrew T. McPhail, Claude H. Yoder, Raymond W. Hillyard

Journal of the Chemical Society Chemical Communications · 1978 · 73 citations · 0 references

Concepts

Natural SciencesChemistryCrystal StructureInorganic ChemistryOrganic ChemistryCrystal ChemistryHeterocycle SynthesisHeterocyclic ChemistryMolecular SymmetryOrganic SynthesisCrystal Structure AnalysisSilicon ChemistrySingle Crystal AnalysisSingle-crystal X-ray Diffraction

Abstract

The compound erroneously reported as NN-bis(chloromethyldimethylsilyl)acetamide has been proven by single-crystal X-ray analysis to be (O–Si)-chloro-[(N-chlorodimethylsilylacetamido)methyl]dimethylsilane.