Chemical Communications · 2010 · 47 citations · 41 references
Natural SciencesChemistryOrganic ChemistryHeterocycle SynthesisHeterocyclic ChemistryOrganic SynthesisMild Reaction ConditionsPalladium CatalystsSilane CouplingSilane Coupling TreatmentSilane FunctionalizationSilanizationSilylation Reactions
The treatment of aryl iodides with tris(trimethylsilyl)silane in the presence of Pd(P(tBu)(3))(2) and the Hünig base leads to the formation of hypersilylated aromatic products in good to excellent yields without cleavage of weak Si-Si bonds under mild conditions.
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Synthesis and Electronic Properties of 9,10-Disilylanthracenes
Soichiro Kyushin, Masanobu Ikarugi, Midori Goto et al. · Organometallics · 1996 · 123 citations