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Spectroscopic description of an unusual protonated ferryl species in the catalase from Proteus mirabilis and density functional theory calculations on related models. Consequences for the ferryl protonation state in catalase, peroxidase and chloroperoxidase

Spectroscopic DescriptionBiochemistryBioenergeticsNatural SciencesEnzyme CatalysisProton TransferProton-coupled Electron TransferStructure-function Enzyme KineticsFerryl Protonation StateChemistryMedicineRedox BiologyProteus Mirabilis