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Picosecond Hydrogen Transfer in the Phenol-(NH<sub>3</sub>)<i><sub>n</sub></i><sub>=1</sub><sub>-</sub><sub>3</sub> Excited State
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Citations
35
References
2000
Year
Electronic Excited StateExcited State PropertyLocalized Excited StateBand OriginsEngineeringPhotochemistryPhysicsNatural SciencesProton TransferShort LifetimesPicosecond Hydrogen TransferPhysical ChemistryExcitation Energy TransferQuantum ChemistryHydrogenChemistryExcited ClustersBiophysics
The phenol−(NH3)n=1,2,3 (S1) lifetimes have been measured near their band origins by a picosecond pump/probe scheme. The very short lifetimes observed reveal that the excited clusters undergo a reactive process, namely the following dissociative hydrogen transfer reaction: PhOH*−(NH3)n → PhO• + NH4(NH3)n-1.
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