Proposal for an International Molybdenum Isotope Measurement Standard and Data Representation

Thomas F. Nägler, Ariel D. Anbar, Corey Archer, Tatiana Goldberg, Gwyneth W. Gordon, Nicolas D. Greber, Christopher Siebert, Yoshiki Sohrin, Derek Vance

Geostandards and Geoanalytical Research · 2013 · 228 citations · 20 references

Concepts

TL;DR

Molybdenum isotopes are widely used in Earth sciences to study ocean and atmospheric oxygenation and are increasingly applied to magmatic, hydrothermal, planetary, and pollution tracing studies. We propose a unified presentation of Mo isotope ratios for mass‑dependent fractionation studies. The proposal defines the δ98/95 Mo of NIST SRM 3134 as +0.25 ‰ and adopts the IAPSO ocean water standard (δ98/95 Mo = +2.34 ± 0.10 ‰) as a secondary reference. This framework allows direct comparison of legacy and future data while preserving canonical δ98/95 Mo values of +2.3 ‰ for seawater and −0.7 ‰ for marine Fe–Mn precipitates.

Abstract

Molybdenum isotopes are increasingly widely applied in Earth Sciences. They are primarily used to investigate the oxygenation of Earth's ocean and atmosphere. However, more and more fields of application are being developed, such as magmatic and hydrothermal processes, planetary sciences or the tracking of environmental pollution. Here, we present a proposal for a unifying presentation of Mo isotope ratios in the studies of mass‐dependent isotope fractionation. We suggest that the δ 98/95 Mo of the NIST SRM 3134 be defined as +0.25‰. The rationale is that the vast majority of published data are presented relative to reference materials that are similar, but not identical, and that are all slightly lighter than NIST SRM 3134. Our proposed data presentation allows a direct first‐order comparison of almost all old data with future work while referring to an international measurement standard. In particular, canonical δ 98/95 Mo values such as +2.3‰ for seawater and −0.7‰ for marine Fe–Mn precipitates can be kept for discussion. As recent publications show that the ocean molybdenum isotope signature is homogeneous, the IAPSO ocean water standard or any other open ocean water sample is suggested as a secondary measurement standard, with a defined δ 98/95 Mo value of +2.34 ± 0.10‰ (2 s ).

References

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