Concepedia

Iodination of Organic Substrates with Halide Salts and H<sub>2</sub>O<sub>2</sub> Using an Organotelluride Catalyst

Michael R. Detty, Donald E. Higgs, Marina I. Nelen

Organic Letters · 2001 · 66 citations · 9 references

DOI

Concepts

Abstract

[figure: see text] Organotelluride 1 is a water-soluble catalyst for the oxidation of iodide with hydrogen peroxide in pH 6 phosphate buffer. In two-phase systems, organic substrates are efficiently iodinated using 0.8 mol % of catalyst. Water-soluble substrates are iodinated without an organic cosolvent.

References

9

Bioinorganic catalysis

László I. Simándi · Reaction Kinetics and Catalysis Letters · 1999 · 487 citations

Regioselective Bromination of Organic Substrates by Tetrabutylammonium Bromide Promoted by V<sub>2</sub>O<sub>5</sub>−H<sub>2</sub>O<sub>2</sub>:  An Environmentally Favorable Synthetic Protocol

Upasana Bora, Gopal Bose, Mihir K. Chaudhuri et al. · Organic Letters · 2000 · 194 citations

, , +13

Mimicking the vanadium bromoperoxidases reactions:Mild and selective bromination of arenes and alkenes in a two-phase system

Valeria Conte, Fulvio Di Furia, Stefano Moro · Tetrahedron Letters · 1994 · 117 citations

, , +5

Simple and efficient chlorination and bromination of aromatic compounds with aqueous TBHP (or H2O2) and a hydrohalic acid

Nivrutti B. Barhate, Anil S. Gajare, Radhika D. Wakharkar et al. · Tetrahedron Letters · 1998 · 106 citations

, , +17

A Mechanism for the Oxidation of Glutathione to Glutathione Disulfide with Organotellurium(IV) and Organoselenium(IV) Compounds. A Stepwise Process with Implications for Photodynamic Therapy and Other Oxidative Chemotherapy

Michael R. Detty, Alan E. Friedman, A. R. Oseroff · The Journal of Organic Chemistry · 1994 · 67 citations

, , +14