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The absolute stereochemistry of some clerodane diterpenoids from Teucrium species
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1981
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Bioorganic ChemistryBiochemistryBiochemical TaxonomyClerodane DiterpenoidsNatural SciencesTeucrin P1Secondary MetaboliteOrganic ChemistryT. GnaphalodesStereoselective SynthesisNeoclerodane SeriesPhytochemistryPharmacologyEnantioselective SynthesisNatural Product Synthesis
The absolute configurations of 19-acetylgnaphalin, and another diterpenoid from T. gnaphalodes, probably identical with teucrin P1, have been determined by X-ray analysis; they belong to the neoclerodane series. Isofruticolone has also been shown to belong to this series.