Concepedia

A well-defined iron(ii) alkoxide initiator for the controlled polymerisation of lactide

V.C. Gibson, E.L. Marshall, Diana Navarro-Llobet, Andrew J. P. White, David J. Williams

Journal of the Chemical Society Dalton Transactions · 2002 · 110 citations · 4 references

DOI

Concepts

Abstract

The three-coordinate iron(II) complex, (But-BDI)FeOBut [But-BDI = HC(C(But)N-2,6-iPr2C6H3)2] is found to be a highly active initiator for the polymerisation of lactide and caprolactone at room temperature.

References

4

Single-Site Catalysts for Ring-Opening Polymerization:  Synthesis of Heterotactic Poly(lactic acid) from <i>rac</i>-Lactide

Ming Cheng, Athula B. Attygalle, Emil B. Lobkovsky et al. · Journal of the American Chemical Society · 1999 · 594 citations

, , +12

Mechanistic Comparison of Cyclic Ester Polymerizations by Novel Iron(III)−Alkoxide Complexes:  Single vs Multiple Site Catalysis

B.J. O'Keefe, Laurie E. Breyfogle, Marc A. Hillmyer et al. · Journal of the American Chemical Society · 2002 · 295 citations

, , +16

A complete table of electronegativities

Elbert J. Little, Mark M. Jones · Journal of Chemical Education · 1960 · 242 citations

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Planar Three-Coordinate High-Spin Fe<sup>II</sup> Complexes with Large Orbital Angular Momentum:  Mössbauer, Electron Paramagnetic Resonance, and Electronic Structure Studies

Hanspeter Andres, Emile L. Bominaar, Jeremy M. Smith et al. · Journal of the American Chemical Society · 2002 · 201 citations

, , +17