ACS Macro Letters · 2011 · 79 citations · 30 references
Natural SciencesMaterials EngineeringMaterials ScienceMaterials ChemistryNanomaterialsPolymer ChemistryCarbon NanomaterialsCarbon NanotubesNanoparticle DispersionsNanotubesPolymer StabilizationPolymeric NanomaterialsCopolymerizationIonic StrengthIonic Strength DependenceIonic Strength EffectsMulti-walled Carbon NanotubesNanoparticle StabilizationPolymer DispersantsStimuli-responsive Behavior
A unique copolymer stabilizer is presented that can be used to stabilize multiwalled carbon nanotubes in aqueous solution to form “smart” dispersions. They showed double stimuli-responsive behavior (in dependence of temperature and ionic strength) and allowed for accurate control of the transition (exfoliated → agglomerated) temperature of nanotubes over a wide temperature range. In spite of its effective dispersion strength, the copolymer was easily synthesized in one step via free radical copolymerization of N -isopropylacrylamide and 1-ethyl-3-vinylimidazolium bromide.
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