Bulletin of the Chemical Society of Japan · 1978 · 26 citations · 13 references
Natural SciencesChemistryCatalysisOrganic ChemistryOrganometallic ChemistryCatalyst DesignCatalytic MechanismsHeterogeneous CatalysisCatalyst Active SitesCatalyst MechanismsCyclopropanation ReactionsEnantioselective CatalysisEnantioselective SynthesisPalladium Catalysts
Abstract Carbenoid decomposition of ethyl diazoacetate in the presence of various palladium complexes as catalysts was found to kinetically depend on the identity of halide ligands. The use of several chiral ligands did not induce appreciable enantioselective catalytic cyclopropanation between ethyl diazoacetate and styrene. The active catalyst species is not under the influence of the chiral ligands but under control of halides which are bound more strongly to the metal.
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Homogeneous catalysis in the decomposition of diazo compounds by copper chelates
H. NOZAKI, Hidemasa Takaya, S. Moriuti et al. · Tetrahedron · 1968 · 310 citations
Kazutoshi Tani, Leo D. Brown, Jamil Ahmed et al. · Journal of the American Chemical Society · 1977 · 165 citations