Transition metal–carbon bonds. Part XXII. Pyrolysis of some methylplatinum(<scp>IV</scp>) complexes - Concepedia

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Transition metal–carbon bonds. Part XXII. Pyrolysis of some methylplatinum(<scp>IV</scp>) complexes

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1969

Year

J. D. Ruddick, Bernard L. Shaw

Journal of the Chemical Society A Inorganic Physical Theoretical

Transition Metal–carbon BondsInorganic ChemistryAcetyl ComplexesNatural SciencesCoordination ComplexMolecular BiologyMolecular ComplexChemistryInorganic SynthesisQuantitative YieldsInorganic Compound

Abstract

Some methylplatinum(IV) complexes of the type [PtXyMe4–yL2](X = halogen; y= 0–3; L = PMe2Ph or AsMe2Ph) have been pyrolysed and the gases evolved and the platinum(II) complexes formed have been identified. Acetyl complexes of the type [PtXMe2(COMe)L2] on pyrolysis give acetone and trans-[PtXMeL2] in quantitative yields.