Concepedia

Non-catalytic conversion of C–F bonds of benzotrifluorides to C–C bonds using organoaluminium reagents

Jun Terao, Misaki Nakamura, Nobuaki Kambe

Chemical Communications · 2009 · 90 citations · 19 references

DOI

Concepts

Abstract

A facile method for the conversion of C-F bonds of benzotrifluorides to C-C bonds has been developed using aluminium reagents in the absence of catalysts.

References

19

Hydrodefluorination of Perfluoroalkyl Groups Using Silylium-Carborane Catalysts

Christos Douvris, Oleg V. Ozerov · Science · 2008 · 578 citations

, , +13

Cross-Coupling Reaction of Alkyl Halides with Grignard Reagents Catalyzed by Ni, Pd, or Cu Complexes with π-Carbon Ligand(s)

Jun Terao, Nobuaki Kambe · Accounts of Chemical Research · 2008 · 368 citations

, , +15

Room-Temperature Catalytic Hydrodefluorination of C(sp<sup>3</sup>)−F Bonds

Valerie Scott, R. Celenligil-Cetin, Oleg V. Ozerov · Journal of the American Chemical Society · 2005 · 323 citations

, , +7

Ni- or Cu-Catalyzed Cross-Coupling Reaction of Alkyl Fluorides with Grignard Reagents

Jun Terao, Aki Ikumi, Hitoshi Kuniyasu et al. · Journal of the American Chemical Society · 2003 · 279 citations

, , +11

Copper‐Catalyzed Cross‐Coupling Reaction of Grignard Reagents with Primary‐Alkyl Halides: Remarkable Effect of 1‐Phenylpropyne

Jun Terao, Hirohisa Todo, Hitoshi Kuniyasu et al. · Angewandte Chemie International Edition · 2007 · 219 citations

, , +9