A New One-Pot Synthesis of Dialkyl Phosphonates from Diazo Compounds and Dialkyl Hydrogen Phosphites

A. M. Polozov, N. A. Polezhaeva, Albert H. Mustaphin, Alexander V. Khotinen, B. A. Arbuzov

Synthesis · 1990 · 47 citations · 0 references

Concepts

Abstract

Bis(acetylacetonato)copper(II) is an effective catalyst for the preparation of dialkyl phosphonates from diazo compounds and dialkyl hydrogen phosphites. This method complements the classical ones and makes 2-dialkoxyphosphoryl-1,3-dicarbonyl compounds available.