Concepedia

Free Radical-Mediated Vinyl Amination:  Access to <i>N,N</i>-Dialkyl Enamines and Their β-Stannyl and β-Thio Derivatives

Erode N. Prabhakaran, Benjamin M. Nugent, Amie L. Williams, Kristen E. Nailor, Jeffrey N. Johnston

Organic Letters · 2002 · 39 citations · 11 references

DOI

Concepts

Abstract

[reaction: see text] The first examples of free radical-mediated vinyl amination are described by nonconventional vinyl radical addition to azomethine nitrogen. This new vinyl amination protocol is mild and provides convenient synthetic access to nonstabilized N,N-dialkyl enamines and tandem bond-forming processes.

References

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