Free Radical-Mediated Vinyl Amination: Access to <i>N,N</i>-Dialkyl Enamines and Their β-Stannyl and β-Thio Derivatives

Abstract

[reaction: see text] The first examples of free radical-mediated vinyl amination are described by nonconventional vinyl radical addition to azomethine nitrogen. This new vinyl amination protocol is mild and provides convenient synthetic access to nonstabilized N,N-dialkyl enamines and tandem bond-forming processes.