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Synthesis and Crystal Structure of [Cd<sub>10</sub>Se<sub>4</sub>(SePh)<sub>12</sub>(PPh<sub>3</sub>)<sub>4</sub>] and [Cd<sub>16</sub>(SePh)<sub>32</sub>(PPh<sub>3</sub>)<sub>2</sub>]
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Citations
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References
1997
Year
Materials ScienceInorganic ChemistryCrystal StructureOrganic SolventEngineeringCluster SciencePhenyl RingsNatural SciencesMolecular BiologyStructure ElucidationPhysical ChemistryCluster ChemistryMain Group ChemistryChemistryCrystallographyCrystal Structure Design
Clusters with and without cavities are formed in the reaction of [CdCl2(PPh3)2] with PhSeSiMe3. Depending on the organic solvent used, [Cd10Se4(SePh)12(PPh3)4] or [Cd16(SePh)32(PPh3)2] (depicted on the right; the cluster is almost completely covered with phenyl rings) crystallizes. The clusters are composed of fused adamantanoid CdSe cages.
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