Efficient Degradation of Toxic Organic Pollutants with Ni₂O₃/TiO₂_-<i>_x</i>B<i>_x</i> under Visible Irradiation

TLDR

TiO₂ has been modified to extend its spectral response into the visible region to promote efficient solar energy use. The study develops a TiO₂ photocatalyst modified by boron doping and Ni₂O₃ addition. The modified catalyst exhibits high visible‑light photocatalytic activity, efficiently degrading and mineralizing toxic organics such as trichlorophenol, 2,4‑dichlorophenol, and sodium benzoate. The dechlorination and mineralization results confirm a visible‑light‑excited photocatalytic pathway.

Abstract

To promote efficient use of solar energy, many studies have focused on the modification of TiO2 to extend its spectral response to visible region. Here we report a combined modification of TiO2 by two components: the nonmetal element boron and the metal oxide Ni2O3. The photocatalyst presents high photocatalytic activity in the visible region, which can efficiently degrade and mineralize toxic organic pollutants such as trichlorophenol (TCP), 2,4-dichlorophenol (2,4-DCP), and sodium benzoate. The dechlorination and mineralization results indicate the photocatalytic pathway via visible light excitation. The study demonstrates that the modification of TiO2 both to extend its spectral response to the visible region and to improve its catalytic efficiency can be achieved by doping with boron, a nonmetal, and Ni2O3, a metal oxide.