Concepedia

Polymer immobilised TEMPO (PIPO): an efficient catalyst for the chlorinated hydrocarbon solvent-free and bromide-free oxidation of alcohols with hypochlorite

Arné Dijksman, Isabel W. C. E. Arends, Roger A. Sheldon

Chemical Communications · 2000 · 125 citations · 10 references

DOI

Concepts

Abstract

PIPO, a readily prepared polymer immobilised TEMPO, can be employed as an efficient recyclable heterogeneous catalyst for the chlorinated hydrocarbon solvent-free and bromide-free bleach oxidation of a variety of alcohols and polyols.

References

10

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Highly selective nitroxyl radical-mediated oxidation of primary alcohol groups in water-soluble glucans

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Selective oxidation of monosaccharide derivatives to uronic acids

Nicola J. Davis, Sabine L. Flitsch · Tetrahedron Letters · 1993 · 226 citations

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Selective oxidation of primary alcohols mediated by nitroxyl radical in aqueous solution. Kinetics and mechanism

Arjan E. J. de Nooy, Arie C. Besemer, H. van Bekkum · Tetrahedron · 1995 · 216 citations

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