Concepedia

Catalytic Enantioselective Hydrogenolysis of [Cr(CO)<sub>3</sub>(5,8‐Dibromonaphthalene)]

E. Peter Kündig, Piyali Datta Chaudhuri, David House, Gérald Bernardinelli

Angewandte Chemie International Edition · 2006 · 56 citations · 17 references

DOI

Concepts

Abstract

Split and run: A study of the asymmetric hydrogenolysis of an aryl-carbon–bromine bond in a naphthalene chromiumtricarbonyl complex shows the use of a new bulky phosphoramidite ligand to yield the product in highly enantiomerically enriched form (see scheme).

References

17

<i>SIR</i>97: a new tool for crystal structure determination and refinement

Angela Altomare, M. C. Burla, Mercedes Camalli et al. · Journal of Applied Crystallography · 1999 · 9.1K citations

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A modular approach for ligand design for asymmetric allylic alkylations via enantioselective palladium-catalyzed ionizations

Barry M. Trost, David L. Van Vranken, Carsten Bingel · Journal of the American Chemical Society · 1992 · 530 citations

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Enantioselective Catalytic Conjugate Addition of Dialkylzinc Reagents using Copper–Phosphoramidite Complexes; Ligand Variation and Non-linear Effects

Leggy A. Arnold, Rosalinde Imbos, Alessandro Mandoli et al. · Tetrahedron · 2000 · 292 citations · Full text

, , +11

Biphenol-Based Phosphoramidite Ligands for the Enantioselective Copper-Catalyzed Conjugate Addition of Diethylzinc

Alexandre Alexakis, Damien Polet, Stéphane Rosset et al. · The Journal of Organic Chemistry · 2004 · 138 citations

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Catalytic asymmetric induction of planar chirality by palladium-catalyzed asymmetric cross-coupling of a meso (arene)chromium complex

Motokazu Uemura, Hikaru Nishimura, Tamio Hayashi · Tetrahedron Letters · 1993 · 103 citations

, , +16