Chemistry Letters · 1982 · 17 citations · 17 references
Natural SciencesChemistryOrganic ChemistryPhysical ChemistryReaction MechanismsCarbene Insertion ReactionsMatrix Effects Interpretation
Abstract C–H insertion process of phenylchlorocarbene, a ground state singlet carbene, is not affected by matrix which generally exerts its effect in C–H insertion of most arylcarbenes. This reveals the origin of the matrix effects on carbene reactions.
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