Concepedia

Synthesis and structures of neutral and cationic β-diketiminatoaluminium methyls†

F. Cosledan, Peter B. Hitchcock, Michael F. Läppert

Chemical Communications · 1999 · 47 citations · 12 references

DOI

Concepts

Abstract

Trimethylaluminium with the β-diketimine H(LL) yields the aluminium complex [Al(LL)Me2], from which the salts [Al(LL)Me(thf)][BMe(C6F5)3]·0.5thf and [Al(LL)Me(OEt2)][B(C6F5)4]·0.5Et2O have been prepared, and crystallographically characterised.

References

12

Highly Active Iron and Cobalt Catalysts for the Polymerization of Ethylene

Brooke L. Small, Maurice Brookhart, Alison M.A. Bennett · Journal of the American Chemical Society · 1998 · 1.5K citations

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Cationic Aluminum Alkyl Complexes Incorporating Amidinate Ligands. Transition-Metal-Free Ethylene Polymerization Catalysts

Martyn P. Coles, Richard F. Jordan · Journal of the American Chemical Society · 1997 · 298 citations

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Polymerization of α-Olefins by Chelating Diamide Complexes of Titanium

John D. Scollard, David H. McConville, Nicholas C. Payne et al. · Macromolecules · 1996 · 255 citations

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Sterically Encumbered (Perfluoroaryl) Borane and Aluminate Cocatalysts for Tuning Cation−Anion Ion Pair Structure and Reactivity in Metallocene Polymerization Processes. A Synthetic, Structural, and Polymerization Study

You‐Xian Chen, M. Metz, Liting Li et al. · Journal of the American Chemical Society · 1998 · 248 citations

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Synthesis and Structures of Mono- and Bis(amidinate) Complexes of Aluminum

Martyn P. Coles, Dale C. Swenson, Richard F. Jordan et al. · Organometallics · 1997 · 236 citations

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