Publication | Closed Access
<i>En Suite</i> Generation of Chromium Carbonyl Arene Complex Substituted Propargylic Cation and Anion Intermediates in Side-Chain Functionalizations
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Citations
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References
2000
Year
Inorganic ChemistryEngineeringBiochemistryNatural SciencesChemical BondOrganometallic ElectrochemistryOrganic ChemistryAnionic SpeciesSide-chain FunctionalizationsChemistryMolecular ChemistryAnion IntermediatesSynthetic ChemistryEnantioselective SynthesisBiomolecular EngineeringPropargyl Cations
The (phenyl)Cr(CO)3 substituent efficiently stabilizes both propargyl cations and anions. In subsequent trapping reactions of the anionic species that can be spectroscopically studied, the regioselectivity depends on the hardness of the attacking electrophile.
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