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Rhodium-Catalyzed Asymmetric Ring-Opening Alkynylation of Azabenzonorbornadienes

82

Citations

51

References

2008

Year

Abstract

Asymmetric ring-opening alkynylation of meso-azabenzonorbornadienes with (triisopropylsilyl)acetylene giving 2-alkynyl-1-aminodihydronaphthalenes took place in high yields with high enantioselectivity in the presence of a rhodium/(R)-DTBM-segphos catalyst.

References

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