4,4′,6,6′-Tetra-Substituted Hydrazo- and Azo-1,3,5-Triazines

Abstract

Abstract The syntheses of 4,4′,6,6′-tetra(amino)- (1), tetra(hydroxylamino)- (2), tetra(hydrazino)- (3), and tetra(azido)hydrazo-1,3,5-triazines (4) are described. Compound (4) was oxidized to 4,4′,6,6′-tetra(azido)azo-1,3,5-triazine (5). The thermal and sensitivity properties of (4) and (5) are reported in addition to all physical properties of new compounds Keywords: triazinessynthesispropertiesazohydrazo Acknowledgments This work was supported by the Joint DOD/DOE Office of Munitions Program for the preparation and characterization of new energetic materials.