Publication | Open Access
Ullmann Condensation Reaction of Haloanthraquinone Derivatives with Amines in Aprotic Solvents
34
Citations
3
References
1977
Year
EngineeringUllmann CondensationOrganic ChemistryUllmann Condensation ReactionChemistryChemical EngineeringCupric OnesAbstract Cuprous CatalystsNovel OrganocatalystsOrganometallic CatalysisCross-coupling ReactionAprotic SolventsHaloanthraquinone DerivativesCatalysisAsymmetric CatalysisEnantioselective SynthesisCatalytic SynthesisHalogenationDerivative (Chemistry)
Abstract Cuprous catalysts were more effective than cupric ones in the Ullmann condensation of haloanthraquinones with amines in aprotic media. In the presence of Cu(I) catalyst, amines with a hydroxyl group (3-amino-1-propanol and 2-aminoethanol) were more reactive than the higher basic butylamine.
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