Angewandte Chemie International Edition · 2011 · 165 citations · 23 references
Natural SciencesChemistryPhysicsMagnetic MaterialsMolecular PhysicsNanomaterialsActinide ChemistryActinide MaterialsMagnetic NanomaterialsMagnetism Of Inorganic CompoundsActinide MagnetismAnisotropyMagnetic HysteresisMagnetic Hysteresis AnalysisMagnetic Memory EffectsMagnetic RelaxationMagnetization In NanostructuresMolecular Magnetism
Selective memory: Using actinides in designing molecular nanomagnets could provide better performance and higher anisotropy barriers, owing to the peculiar properties of the 5f electron shell. Neptunocene is found to display an open magnetic hysteresis cycle at low temperatures (see picture), and interaction with the hyperfine degrees of freedom determines whether the magnetic relaxation is fast or slow at a given field value.
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Magnetic bistability in a metal-ion cluster
Roberta Sessoli, Dante Gatteschi, Andréa Caneschi et al. · Nature · 1993 · 4.3K citations
Natural Sciences, Chemistry, Physics +14
Molecular spintronics using single-molecule magnets
Lapo Bogani, Wolfgang Wernsdorfer · Nature Materials · 2008 · 3.1K citations