A New Alkoxyiodination and Nitratoiodination of Olefins Using lodine-Cerium(IV) Ammonium Nitrate

C. Akira Horiuchi, Yoshihiko Nishio, Dan Gong, Takanori Fujisaki, Shinji Kiji

Chemistry Letters · 1991 · 20 citations · 2 references

Concepts

Abstract

Abstract Reactions of cycloolefins with iodine-cerium(IV) ammonium nitrate in alcohols (methanol, ethanol, 1-propanol, and 2-propanol) under reflux gave the corresponding vicinal alkoxyiodocycloalkanes in good yields. In the case of t-butyl alcohol, trans-iodo nitrates were obtained.

References

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