Publication | Open Access
A Simple Synthetic Method for 2,15-Hexadecanedione from a Butadiene Telomer
32
Citations
6
References
1978
Year
Combinatorial ChemistryEngineeringOrganic ChemistryChemistryHeterocycle ChemistryTerminal Double BondChemical EngineeringNovel OrganocatalystsOrganometallic CatalysisButadiene TelomerCatalysisKolbe ElectrolysisCatalytic SynthesisBiomolecular EngineeringHeterocyclicElectrosynthesisHigh YieldMolecular CatalysisSynthetic Chemistry
Abstract The terminal double bond of 3,8-nonadienoate was oxidized to methyl ketone with a catalyst system of PdCl2/CuCl/O2 and the internal double bond was reduced to give 8-oxononanoate, which was hydrolyzed to 8-oxononanoic acid. The Kolbe electrolysis of the acid produced 2,15-hexadecanedione in a high yield.
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