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Chemie polyfunktioneller Liganden, 56 [1]. Darstellung von N-Deutero-bis(diphenylphosphino)amin, sowie schwingungsspektroskopischer Vergleich mit Bis(diphenylphosphino)amin und Lithium-bis(diphenylphosphino)amid / Chemistry of Polyfunctional Ligands, 56 [1]. Preparation of N-Deutero-bis(diphenylphosphino)amine, as well as the Vibrational Spectroscopic Comparison with Bis(diphenylphosphino)amine and Lithium-bis(diphenylphosphino)amid

Jochen Eilermann, Martin Lietz

Zeitschrift für Naturforschung B · 1980 · 30 citations · 0 references

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Abstract

Abstract Bis(diphenylphosphino)amine, [(C 6 H 5 )P 2 NH (1), can be metallated with n-butyl-lithium to hthium-bis(diphenylphosphino)amid, [(C 6 H 5 )P 2 NLi (2), It reacts with CH 3 OD to give N-Deutero-bis(diphenylphosphino)amine, [(C 6 H 5 )P 2 ND (3). The compounds were characterized by infrared, Raman, 1 H and 31 P NMR spectroscopy.