Synthesis of polymer precursors of electroactive materials by SET-LRP

Abstract

SET-LRP is used for the controlled copolymerisation of 2,2,6,6-tetramethylpiperidin-4-yl methacrylate (TMPM) with 3-azidopropyl methacrylate (AzPMA), followed by the oxidation of TMPM to produce electroactive poly(TEMPO methacrylate) (PTMA).