The role of atropisomers on the photo-reactivity and fatigue of diarylethene-based metal–organic frameworks

Ian M. Walton, Jordan M. Cox, Cassidy A. Benson, Dinesh G. Patel, Yu‐Sheng Chen, Jason B. Benedict

New Journal of Chemistry · 2015 · 129 citations · 41 references

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Abstract

Stabilization of unfavorable rotational isomers within the nanoporous crystalline matrix reduces the useful lifetime of this photo-switchable material.

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