First measurement of the nonlinear coefficient for Gd_1−XLu_XCa_4O(BO_3)_3 and Gd_1−XSc_XCa_4O(BO_33)_3 crystals

Abstract

The effective nonlinear coefficient and temperature acceptance bandwidth of three Lu and Sc co-doped GdCa(4)O(BO(3))(3) type nonlinear crystals were measured. NCPM for SHG in to the blue-UV spectral region can be obtained by controlling the co-dopant concentration. Measurements were based on intra-cavity SHG of a CW Ti:Sapphire laser, and the effective nonlinear coefficients were found to be in the range of 0.5 to 0.6 pm/V for the three crystals used. The FWHM temperature acceptance bandwidth was measured to be more than 35 degrees C using a 6 mm long Gd(0.871)Lu(0.129)Ca(4)O(BO(3))(3) crystal. A maximum of 115 mW at 407.3 nm in a single direction was measured using a 6.5 mm long Gd0.96Sc0.04Ca(4)O(BO(3))(3) crystal.