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A novel 2D net-like supramolecular polymer constructed from Ln<sub>6</sub>Cu<sub>24</sub>node and trans-Cu(Gly)<sub>2</sub>bridge
83
Citations
18
References
2004
Year
Net-like Supramolecular PolymerHigh-nuclear 3D–4fEngineeringSupramolecular AssemblyNovel 2DChemistryMolecular PolymerPolymersLinear Chain CompoundMacromolecular EngineeringHeterometallic ClusterHybrid MaterialsPolymer ChemistryMaterials ScienceInorganic ChemistryLn6cu24 Octahedral ClusterMolecular EngineeringSupramolecular PolymerNanomaterialsSelf-assemblyPolymer ScienceFunctional PolymerFunctional MaterialsMetal Chain CompoundPolymer Synthesis
A 2D net-like lanthanide-copper heterometallic supramolecular network {Ln6Cu27} 1 was synthesized with Ln6Cu24 octahedral cluster as the node and trans-Cu(glycinato)2 group as the linker. The compound represents the first example of 2D polymer with high-nuclear 3d–4f heterometallic cluster as the node.
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