Chemical Communications · 2001 · 37 citations · 21 references
Natural SciencesChemistryCatalysisOrganic ChemistryAlkyne ComplexesCatalyst SynthesisCatalytic MaterialsChiral RecognitionChiral SeparationOrganic SynthesisAldehydesAsymmetric Catalyst DesignChiral Catalyst DesignDesymmetrization By ReductionEnantioselective CatalysisEnantioselective Catalyst DesignEnantioselective Cross-couplingEnantioselective Synthesis
Highly enantioselective silylcyanation of aliphatic and aromatic aldehydes was achieved by using a 1,2-diphenylethylenediamine linked chiral Ti(IV) complex as the catalyst.
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