Synthesis and luminescence behaviour of novel heterodecanuclear silver(<scp>i</scp>)–rhenium(<scp>i</scp>) alkynyl complexes. X-Ray crystal structures of [Ag<sub>6</sub>(μ-dppm)<sub>4</sub>{μ<sub>3</sub>-CCCC–Re(Me<sub>2</sub>bpy)(CO)<sub>3</sub>}<sub>4</sub>](PF<sub>6</sub>)<sub>2</sub>and [Ag<sub>6</sub>(μ-dppm)<sub>4</sub>{μ<sub>3</sub>-CCCC–Re(Br<sub>2</sub>phen)(CO)<sub>3</sub>}<sub>4</sub>](PF<sub>6</sub>)<sub>2</sub> - Concepedia

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Synthesis and luminescence behaviour of novel heterodecanuclear silver(<scp>i</scp>)–rhenium(<scp>i</scp>) alkynyl complexes. X-Ray crystal structures of [Ag<sub>6</sub>(μ-dppm)<sub>4</sub>{μ<sub>3</sub>-CCCC–Re(Me<sub>2</sub>bpy)(CO)<sub>3</sub>}<sub>4</sub>](PF<sub>6</sub>)<sub>2</sub>and [Ag<sub>6</sub>(μ-dppm)<sub>4</sub>{μ<sub>3</sub>-CCCC–Re(Br<sub>2</sub>phen)(CO)<sub>3</sub>}<sub>4</sub>](PF<sub>6</sub>)<sub>2</sub>

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Citations

24

References

2003

Year

Vivian Wing‐Wah Yam, Wing-Yin Lo, Nianyong Zhu

Chemical Communications

Abstract

A novel series of luminescent heterodecanuclear mixed-metal alkynyl complexes, [Ag6(mu-dppm)4[mu3-C[triple bond]CC[triple bond]C-Re(N--N)(CO)3]4](PF6)2, (N--N = tBu2bpy, Me2bpy, phen, Br2phen), have been successfully synthesized; the X-ray crystal structures of [Ag6(mu-dppm)4[mu3-C[triple bond]CC[triple bond]C-Re(Me2bpy)(CO)3]4](PF6)2 and [Ag6(mu-dppm)4[mu3-C[triple bond]CC[triple bond]C-Re(Br2phen)(CO)3]4](PF6)2 have also been determined.

References

	Year	Citations

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