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Claisen Orthoester Rearrangement Reaction with Secondary and Tertiary Allylic Alcohols: Synthesis of 1,2 Secochrysanthemates and Their Structural Analogues
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Citations
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References
1990
Year
Structural AnaloguesBioorganic ChemistryEngineeringNatural SciencesChemical DerivativeOrganic ChemistryA Simple RouteSynthetic ChemistryStereoselective SynthesisChemistryNatural Product SynthesisTertiary Allylic AlcoholsSeco-chrysanthemic AcidEnantioselective SynthesisBiomolecular EngineeringTheir Structural Analogues
Abstract A simple route is described for the synthesis of 1,2 Seco-chrysanthemic acid and their structural analogues, employing Claisen orthoester rearrangement reaction in the key-step of synthesis. These acids have been prepared with a view to evaluating some of the esters prepared from them for possible insecticidal and other biological properties.
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