Concepedia

Bis[hydrotris(pyrazol-1-yl)borato]titanium(II): a stable Tp2M complex of singular reactivity.

A. Kayal, Joshi Kuncheria, Sonny C. Lee

Chemical Communications · 2001 · 22 citations · 13 references

DOI

Concepts

Abstract

Tp2Ti [Tp = hydrotris(pyrazol-1-yl)borate] is a stable hard donor complex of divalent titanium that shows controlled reaction chemistry with simple chalcogen oxidants.

References

13

Boron-Pyrazole Chemistry

Swiatoslaw Trofimenko · Journal of the American Chemical Society · 1966 · 524 citations

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Titanium(II), -(III), and -(IV) Complexes Supported by Benzamidinate Ligands

J.R. Hagadorn, John Arnold · Organometallics · 1998 · 154 citations

, , +15

Side-on versus end-on coordination of dinitrogen to titanium(II) and mixed-valence titanium(I)/titanium(II) amido complexes

Robbert Duchateau, Sandro Gambarotta, Nohma Beydoun et al. · Journal of the American Chemical Society · 1991 · 115 citations · Full text

, , +9

Reductive elimination pathways to low valent titanium aryl oxide complexes

Loren D. Durfee, Phillip E. Fanwick, Ian P. Rothwell et al. · Journal of the American Chemical Society · 1987 · 91 citations

, , +8

[Cp<sub>2</sub>Ti(PMe<sub>3</sub>)<sub>2</sub>]—A Versatile Source of Titanocene Derivatives

Lawrence B. Kool, Marvin D. Rausch, Helmut G. Alt et al. · Angewandte Chemie International Edition in English · 1985 · 90 citations

, , +8