Publication | Closed Access
Conjugation‐Induced Rigidity in Twisting Molecules: Filling the Gap Between Aggregation‐Caused Quenching and Aggregation‐Induced Emission
340
Citations
36
References
2015
Year
Supramolecular AssemblyChemistryAggregation‐induced EmissionSingle Molecule BiophysicsSingle MoleculeConjugation-induced RigidityBiophysicsSolid StatesMolecular ConformationsPhysicsConformational StudyPhysical ChemistryMolecular AggregateQuantum ChemistryGap BetweenConjugation‐induced RigidityNatural SciencesMolecular SwitchMolecular BiophysicsMolecule-based Material
Conjugation-induced rigidity in twisting molecules provides a new facile but effective avenue toward solution and solid dual-state efficient luminogens. While conjugation rigidifies the molecular conformations in solution, the twisting structure prevents or alleviates detrimental close molecular packing in the solid states, thus synergistically yielding high efficiencies in both solution and solid states.
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