Chemical Science · 2015 · 216 citations · 40 references
Natural SciencesChemistryMaterials ScienceElectrochemistryMaterials ChemistryNanomaterialsElectrolyte MaterialsInorganic MaterialsIon Transport In ElectrolytesIon-conducting MaterialsIonic ConductivityIonic ConductorsElectrochemical ReactionsElectrolytesIonic ConductionIonic Liquid Electrolyte MaterialsIonic Liquid ElectrolytesIonic LiquidsMetal-organic FrameworksMicroporous Materials
, H(MeIM) = 2-methylimidazole) as the IL and the MOF, respectively. While the ionic conductivity of bulk EMI-TFSA showed a sharp decrease arising from freezing, the EMI-TFSA@ZIF-8 showed no marked decrease because there was no phase transition. The ionic conductivity of EMI-TFSA@ZIF-8 was higher than that of bulk EMI-TFSA below 250 K. This result points towards a novel method by which to design electrolytes for electrochemical devices such as batteries that can operate at low temperatures.
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