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A novel organic-inorganic hybrid material with fluorescent emission: [Cd(PT)(H<sub>2</sub>O)]<sub>n</sub>(PT = phthalate)
116
Citations
59
References
2003
Year
EngineeringPt LigandsOrganic ChemistryChemistryStrong Fluorescent EmissionChemical EngineeringFluorescent EmissionHoneycomb FrameworkMetal-organic PolyhedronHybrid MaterialsMaterials ScienceInorganic ChemistryPhotochemistryCovalent Bonded FrameworkOrganic MaterialsSelf-assemblyCoordination PolymerMolecule-based MaterialFunctional MaterialsPhosphorescenceOrganic-inorganic Hybrid Material
The novel organic-inorganic hybrid material [Cd(PT)(H2O)]n (1; PT = phthalate) has been hydrothermally synthesized. The X-ray diffraction study reveals that 1 exhibits an interesting two-dimensional (2D) honeycomb framework constructed from [CdO7] single helical chains linked via oxygen atoms of the PT ligands, which adopt the μ6-bridging coordination mode. A study of the physical properties of 1 demonstrates that it exhibits a strong fluorescent emission in the solid state at room temperature.
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