Controlled monomer insertion into polymer main chain: synthesis of sequence ordered polystyrene containing thiourethane and trithiocarbonate units by the RAFT processElectronic supplementary information (ESI) available: 1H and 13C-NMR spectra of polymer precursor 4 and polymer 5. See http://www.rsc.org/suppdata/cc/b2/b205523f/

Abstract

A polymer having a trithiocarbonate moiety in the main chain was applied as a polymeric precursor to the synthesis of a sequence ordered polymer by insertion polymerization of styrene into the main chain by a RAFT mechanism.