Die Angewandte Makromolekulare Chemie · 1971 · 26 citations · 7 references
Natural SciencesChemistryMaterials ScienceMaterials ChemistryPolymer ChemistryPolymer MaterialsFree-radical PolymerizationPolymer Physical ChemistryPolymerization ChemistryPolymerization KineticsPolymerization ProcessesPolymerization Temperature EffectsAqueous Reaction MediaChemical PolymerizationCopper Ion MechanismsFree Radical GenerationFree Radical KineticsInitiationPolymerization MechanismsTemperature Dependence Of Polymerization
Abstract Polymerization of methyl methacrylate was carried out in the presence of nylon‐6 and a trace amount of copper ion, together with or without carbon tetrachloride in aqueous media. The polymerization was found to proceed with a free radical mechanism, and the rate was largely accelerated with increase of copper ion concentration in the case where carbon tetrachloride was present, while the rate tends to become slower in the absence of carbon tetrachloride. Effect of the temperature as well as the amounts of nylon, monomer and water on the rate of polymerization was also studied. From the results obtained, the initiation mechanism was discussed.
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Determination of Molecular Weight of Nylon
J. E. Waltz, G. B. Taylor · Analytical Chemistry · 1947 · 154 citations
Minoru Imoto, Kiichi Takemoto, Hiroyuki Sutoh · Die Makromolekulare Chemie · 1967 · 30 citations
Minoru Imoto, Yoshio Iki, Masayoshi Kinoshita et al. · Die Makromolekulare Chemie · 1969 · 20 citations
Minoru Imoto, Atsushi Tanaka, Kunihiro Ueno et al. · Die Angewandte Makromolekulare Chemie · 1971 · 15 citations