Publication | Closed Access
A building block approach to the synthesis of organic–inorganic oxide materials: the hydrothermal synthesis and network structure of [{Ni<sub>4</sub>(tpypyz)<sub>3</sub>}{Mo<sub>5</sub>O<sub>15</sub>(O<sub>3</sub>PCH<sub>2</sub>CH<sub>2</sub>PO<sub>3</sub>)}<sub>2</sub>]·23H<sub>2</sub>O (tpypyz = tetra-2-pyridylpyrazine)
102
Citations
9
References
2003
Year
The hydrothermal reaction of MoO3, [Ni(CH3CO2)2] x 4H2O, tpypyz, ethylenediphosphonic acid and water yields the 2D material [[Ni4(tpypyz)3][Mo5O15(O3PCH2CH2PO3)]2] x 23H2O (1 x 23H2O), constructed from [Mo5O15(O3PCH2CH2PO3)]4- clusters linked in one-dimension through the ethylene tethers of the diphosphonate component; these molybdodiphosphonate chains are in turn linked into a 2D network through the tetranuclear secondary metal-ligand subunit [Ni4(tpypyz)3]8+.
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