Concepedia

Di-μ-iodo-bis{[methyltris(methylthiomethyl)silane-κ<sup>2</sup><i>S,S</i>′]copper(I)}

H.W. Yim, Daniel Rabinovich, Kin‐Chung Lam, James A. Golen, Arnold L. Rheingold

Acta Crystallographica Section E Structure Reports Online · 2003 · 15 citations · 3 references

DOI

Concepts

Abstract

The mol­ecule of the title compound, [Cu2I2(C7H18S3Si)2], is dimeric. It lies on an inversion center and contains roughly tetrahedral copper centers surrounded by two thio­ether groups and two bridging iodo ligands. The Cu⋯Cu separation, 2.862 (2) Å, is indicative of a weak interaction between the two metal atoms and is not unusual for this type of compound.

References

3

Crown Thioether Complexes of Ag<sup>I</sup> and Cu<sup>I</sup>: The Crystal Structures of [{Ag<sub>3</sub>L<sub>3</sub>}AgL{AgL<sub>2</sub>}](ClO<sub>4</sub>)<sub>4</sub> and [LCuI] (L = 1, 4, 7‐Trithiacyclononane)

Heinz‐Josef Küppers, Karl Wieghardt, Yi‐Hung Tsay et al. · Angewandte Chemie International Edition in English · 1987 · 75 citations

, , +17

Tris[(alkylthio)methyl]silanes:  Syntheses and Structures of Chromium, Molybdenum, and Tungsten Complexes with a Tripodal Thioether Ligand

H.W. Yim, Linh M. Tran, E.D. Dobbin et al. · Inorganic Chemistry · 1999 · 39 citations

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One-Dimensional Copper(I) Coordination Polymers Based on a Tridentate Thioether Ligand

H.W. Yim, Linh M. Tran, E.E. Pullen et al. · Inorganic Chemistry · 1999 · 30 citations

, , +16