CrystEngComm · 2015 · 22 citations · 65 references
Natural SciencesChemistryCrystal StructureMagnetic MaterialsMolecular PhysicsMagnetism Of Inorganic CompoundsRelaxation MechanismsTransition Metal ChemistryTransition Metal ComplexesAnisotropyCoordination Compound MagnetismMagnetic Properties Of Transition Metal ComplexesMagnetic RelaxationMagnetic Relaxation MeasurementsMolecular MagnetismPyridine ChemistrySingle-ion Anisotropy
A new 1D Dy3+ complex based on β-diketone, namely, [Dy(L)3(H2O)]·0.5CH3OH·0.5H2O (1) (HL = 1-phenyl-3-(4′-pyridyl-N-oxide)-propane-1,3-dione) has been designed and synthesized by the combination of β-diketone and pyridine-N-oxide group. The magnetic study indicates the compound's slow magnetic relaxation originating from the single-ion behavior of Dy3+ with strong anisotropy, which is further supported by theoretical calculations.
65
Magnetic bistability in a metal-ion cluster
Roberta Sessoli, Dante Gatteschi, Andréa Caneschi et al. · Nature · 1993 · 4.3K citations
Natural Sciences, Chemistry, Physics +14
High-spin molecules: [Mn12O12(O2CR)16(H2O)4]
Roberta Sessoli, Hui Lien Tsai, Ann R. Schake et al. · Journal of the American Chemical Society · 1993 · 2.3K citations
Natural Sciences, Chemistry, Physics +11