Lanthanide(<scp>iii</scp>) morpholine 4-dithiocarbamate complexes: Pr(<scp>iii</scp>) derivative shows first example of polymeric lanthanide(<scp>iii</scp>) dithiocarbamate

Abstract

Polymeric and discrete Ln(<sc>iii</sc>) morpholine 4-dithiocarbamate complexes [Ln(Phen)(Mph-Dtc)₃]<italic>x</italic>·CH₂Cl₂ [Ln = Pr (<bold>1</bold>), Nd (<bold>2</bold>) and Eu (<bold>3</bold>); Mph-Dtc = morpholine 4-dithiocarbamate; <italic>x</italic> = 2 (<bold>1</bold>) or 1 (<bold>2</bold>, <bold>3</bold>)] have been synthesized and characterized.