Applied Physics Letters · 2004 · 1.5K citations · 15 references
Natural SciencesMaterials EngineeringMaterials ScienceCeramic MaterialsCeramicsSolid State PhysicsFerroelectric CeramicsFerroelectric MaterialsInorganic MaterialsPerovskite MaterialsPiezoelectric CeramicsPiezoelectric MaterialsLead-free Piezoelectric CeramicsLead-free PiezoelectricsMorphotropic Phase BoundaryPerovskite Crystal StructurePiezoelectric CrystalsPiezoelectric PropertiesSintering BehaviorTetragonal System
Lead‑free piezoelectric ceramics (1−x)(Na0.5K0.5)NbO3–xLiNbO3 (x=0.04–0.20) were synthesized by ordinary sintering. The ceramics exhibit an orthorhombic–tetragonal morphotropic phase boundary between x=0.05 and 0.07, with d33 values of 200–235 pC/N, planar and thickness electromechanical coefficients of 38–44 % and 44–48 %, Curie temperatures 452–510 °C, and overall superior high‑temperature piezoelectric performance compared to conventional Pb(Zr,Ti)O3.
Lead-free piezoelectric ceramics (1−x)(Na0.5K0.5)NbO3–xLiNbO3 {[Lix(Na0.5K0.5)1−x]NbO3} (x=0.04–0.20) have been synthesized by an ordinary sintering technique. The materials with perovskite structure is orthorhombic phase at x⩽0.05 and becomes tetragonal phase at x⩾0.07, a phase K3Li2Nb5O15 with tetragonal tungsten bronze structure begins to appear at x=0.08 and becomes dominant with increasing the content of LiNbO3. A morphotropic phase boundary between orthorhombic and tetragonal phases is found in the composition range 0.05<x<0.07. Analogous to Pb(Zr,Ti)O3, the piezoelectric and electromechanical properties are enhanced for compositions near the morphotropic phase boundary. Piezoelectric constant d33 values reach 200–235pC∕N. Electromechanical coefficients of the planar mode and the thickness mode reach 38%–44% and 44%–48%, respectively. The Curie temperatures (TC) of [Lix(Na0.5K0.5)1−x]NbO3 (x=0.04–0.20) are in the range of 452–510°C, at least 100°C higher than that of conventional Pb(Zr,Ti)O3. Our results show that [Lix(Na0.5K0.5)1−x]NbO3 is a good lead-free high-temperature piezoelectric ceramic.
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