Chinese Physics · 2001 · 11 citations · 0 references
Natural SciencesMaterials SciencePhysicsCondensed Matter PhysicsCrystal StructureMaterials CharacterizationCrystal ChemistryMagnetic Properties Of SolidsMagnetism In SolidsMetal MaterialsMetalsSuperconducting MaterialsCarbon Content AnalysisHexagonal LatticesLattice ParametersMagnesium AlloysPhase Transition TemperaturePowder X-ray DiffractionSuperconducting PropertiesX-ray Diffraction Analysis
In this paper, we reported the structural properties and superconductivity of Mg(B1-xCx)2 compounds. Powder x-ray diffraction results indicate that the samples crystallize in a hexagonal AlB2-type structure. Due to the chemical activity of Mg powders, a small amount of MgO impurity phase was detected by x-ray diffraction. The lattice parameters decrease slightly with increasing carbon content. Magnetization measurements indicate the non-stoichiometry of MgB2 has no influence on the superconducting transition temperature and the transition temperature width. The addition of carbon results in a decrease of Tc and an increase in the superconducting transition width, implying the loss of superconductivity.