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A Metal‐Free Route to CF<sub>3</sub>‐Containing Oxindoles by PhI(OAc)<sub>2</sub>‐Mediated Trifluoromethylation of <i>N</i>‐Arylacrylamides with TMSCF<sub>3</sub>
60
Citations
45
References
2013
Year
Useful Cf 3Chemical EngineeringEngineeringMetal‐free RouteFluorous SynthesisOrganic ChemistryChemistryTmscf 3Efficient Phi
Abstract A mild and efficient PhI(OAc) 2 ‐mediated trifluoromethylation reaction of N ‐arylacrylamides with TMSCF 3 under metal‐free conditions was developed. This method provides convenient access to a variety of useful CF 3 ‐containing oxindoles in moderate to good yields.
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