Phase transition in Sr0.75Ba0.25NbO3 near the Curie temperature

Abstract

Strontium barium niobate has the tungsten-bronze structure with a tetragonal unit cell, and it exhibits negative thermal expansion along the c axis between −120°C and room temperature while having a positive thermal expansion along the a axis for the same temperature range. At higher temperatures, close to the Curie temperature and above, the negative thermal expansion along the c axis changes to positive thermal expansion. The a axis lattice parameter as a function of temperature shows a change in slope at the Curie temperature. These results indicate the presence of a second-order phase transition near the Curie temperature.